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22 changes: 17 additions & 5 deletions mite_data/data/MITE0000097.json
Original file line number Diff line number Diff line change
Expand Up @@ -26,6 +26,17 @@
"0000-0001-6534-6609"
],
"comment": "Replaced retired UniProtKB ID with UniParc ID"
},
{
"version": "3",
"date": "2026-02-27",
"contributors": [
"AAAAAAAAAAAAAAAAAAAAAAAA"
],
"reviewers": [
"0000-0001-6534-6609"
],
"comment": "Added reaction description, changed tailoring term from oxidation to dehydrogenation."
}
],
"enzyme": {
Expand All @@ -36,23 +47,24 @@
],
"databaseIds": {
"uniprot": "UPI000D213889",
"genpept": "AVT42378.1",
"mibig": "BGC0001476"
"genpept": "AVT42378.1"
}
},
"reactions": [
{
"tailoring": [
"Oxidation"
"Dehydrogenation"
],
"description": "Dehydrogenates (oxidates) pseudouridine in the pseudouridimycin pathway.",
"reactionSMARTS": "[#8:1]-[#6:2]/[#6@@:3]1-[#6@@:8](\\[#8:9])-[#6@@:6](\\[#8:7])-[#6@:5](/[#6:10]2:[#6:16](=[#8:17]):[#7:15]:[#6:13](=[#8:14]):[#7:12]:[#6:11]:2)-[#8:4]-1>>[#8:9]\\[#6@:8]1-[#6@@:6](\\[#8:7])-[#6@:5](/[#6:10]2:[#6:16](=[#8:17]):[#7:15]:[#6:13](=[#8:14]):[#7:12]:[#6:11]:2)-[#8:4]-[#6@@:3]-1/[#6:2]=[#8:1]",
"reactions": [
{
"substrate": "O=c1[nH]cc([C@@H]2O[C@H](CO)[C@@H](O)[C@H]2O)c(=O)[nH]1",
"products": [
"O=C[C@H]1O[C@@H](c2c[nH]c(=O)[nH]c2=O)[C@H](O)[C@@H]1O"
],
"isIntermediate": false
"isIntermediate": true,
"description": "Dehydrogenates pseudouridine to pseudouridine aldehyde."
}
],
"evidence": {
Expand All @@ -65,4 +77,4 @@
}
}
]
}
}